Repozytorium

Constructing CrIII-centered heterometallic complexes: [Ni6IICrIII] and [Co6IICrIII] wheels.

Autorzy

Foteini E. Kakaroni

Alexandra Collet

Eirini Sakellari

Demetrios I. Tzimopoulos

Miłosz Siczek

Tadeusz Lis

Mark Murrie

Constantinos J. Milios

Rok wydania

2018

Czasopismo

Dalton Transactions

Numer woluminu

47

Strony

58-61

DOI

10.1039/C7DT04043A

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The solvothermal reaction between Cr(acac)3, MCl2·6H2O (M = Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [MII6Cr(HLzw)6(HL)6]·3Cl (M = Ni, 1; Co, 2), with the nickel analogue displaying an S = 9/2 spin ground-state.

Adres publiczny

http://dx.doi.org/10.1039/C7DT04043A

Strona internetowa wydawcy

https://www.rsc.org/

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