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Inne
Catalytic and Antitubercular Activities of Multifunctional Copper(II)–Schiff Base Complexes: Insights into Structure, Theoretical Calculations, and Physicochemical Behavior
Autorzy
Rok wydania
2026
Czasopismo
Numer woluminu
65
Strony
11577-11591
DOI
10.1021/acs.inorgchem.5c05547
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Three copper(II) complexes featuring tridentate ONO donor Schiff base ligands were synthesized and thoroughly characterized by X-ray crystallography, spectroscopy, and electrochemical methods. Density functional theory (DFT) calculations provided insights into their electronic structures and ligand–metal interactions. Complex 1 exhibited moderate catalytic activity toward the selective oxidation of toluene and styrene under mild conditions. Biological assays demonstrated measurable antimycobacterial effects against drug-sensitive and -resistant Mycobacterium tuberculosis strains, while combination studies with standard anti-TB drugs revealed mainly additive or indifferent interactions. These results highlight the promise of these copper(II) Schiff-base complexes as multifunctional agents with catalytic and therapeutic applications.
Słowa kluczowe
Aromatic compounds, Ligands, Molecules, Oxidation, Styrenes
Adres publiczny
http://dx.doi.org/10.1021/acs.inorgchem.5c05547
Strona internetowa wydawcy
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