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Inne
Characterization of a mixed-valence Ru(II)/Ru(III) ion-pair complex. Unexpected high-frequency electron paramagnetic resonance evidence for Ru(III)–Ru(III) dimer coupling.
Autorzy
Rok wydania
2020
Czasopismo
Numer woluminu
59
Strony
8609-8619
DOI
10.1021/acs.inorgchem.0c01068
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
In this contribution, we report the synthesis and full characterization ofthefirst mixed-valence Ru(II)/Ru(III) ion-pair complex, [RuII(bipy)2(pic)]+[cis-RuIIICl2(pic)2]−, in the solid state and in aqueous solution, where bipy = 2,2′-bipyridine and pic−= picolinate. In addition, unexpected high-frequency electronparamagnetic resonance evidence for interactions between two neighboring Ru(III)ions, resulting in a triplet state,S= 1, was found.
Słowa kluczowe
Crystals, X-rays, Ligands, Ions, Electron paramagnetic resonance spectroscopy
Adres publiczny
http://dx.doi.org/10.1021/acs.inorgchem.0c01068
Strona internetowa wydawcy
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