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A chloro-bridged dinuclear phosphinitopalladium complex, di-μ-chloro-bis[(diphenoxyphosphinite-κP)(diphenoxyphosphinito-κP)palladium(II)].

Autorzy

Andrzej Gniewek

Iweta Pryjomska-Ray

Anna M. Trzeciak

Józef J. Ziółkowski

Tadeusz Lis

Rok wydania

2006

Czasopismo

Acta Crystallographica Section C: Structural Chemistry

Numer woluminu

C62

Strony

m491-m494

DOI

10.1107/S0108270106034500

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The title compound, [Pd2(C12H10O3P)2Cl2(C12H11O3P)2], consists of a dinuclear μ-chloro-bridged palladium unit with two diphenoxy­phosphinite groups per Pd atom, linked together by a hydrogen bond. The asymmetric unit contains one half of the mol­ecule, with the other half generated by an inversion centre. The geometry around the P atoms may be described as distorted tetra­hedral. Adjacent mol­ecules of the complex are linked by weak C—H⋯O and C—H⋯Cl hydrogen bonds. The structure is additionally stabilized by π–π stacking inter­actions between the aryl rings. These inter­actions form a herring-bone pattern in the crystal structure.

Adres publiczny

http://dx.doi.org/10.1107/S0108270106034500

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