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A pentanuclear bimetallic complex of manganese(II) and aluminium(III) ions: tetra-μ2-iodido-iodidobis(μ3-2-methoxyethanolato)bis(μ2-2-methoxyethanolato)dimethyl(tetrahydrofuran-κO)aluminium(III)tetramanganese(II).
Autorzy
Rok wydania
2007
Czasopismo
Acta Crystallographica Section C: Structural Chemistry
Numer woluminu
C63
Strony
m501-m503
DOI
10.1107/S0108270107046896
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The molecule of the title compound, [Mn(4)Al(CH(3))(2)(C(3)H(7)O(2))(4)I(5)(C(4)H(8)O)], contains one Al(III) and four Mn(II) ions. Two Mn atoms are five-coordinate in the form of a trigonal bipyramid or a square pyramid. The two other Mn atoms are six-coordinate with an octahedral geometry. The fourcoordinate Al atom is linked to the manganese core by mu-O(alkoxo) bridges, forming an almost planar five-membered ring.
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