Repozytorium

Theoretical study of anharmonic resonances in HBS+

Autorzy

Małgorzata Biczysko

Riccardo Tarroni

Rok wydania

2002

Czasopismo

Molecular Physics

Numer woluminu

100

Strony

3667-3676

DOI

10.1080/00268970210161467

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

A theoretical study of spin-rovibronic levels of HBS+ in the X2II ground state is reported. Vibronic energy levels are calculated variationally using highly accurate full dimensional ab initio potential energy surfaces. All experimental levels are reproduced within 15 cm−1, and predictions of rovibronic levels up to 4000 cm−1 for four isotopomers are provided. Anharmonic resonances induced by the Renner-Teller effect and strong spin-orbit coupling are analysed in detail.

Adres publiczny

http://dx.doi.org/10.1080/00268970210161467

Podobne publikacje
2000

A theoretical study of the reaction of Ti+ with ethane.

Moc Jerzy, Fedorov D. G., Gordon M. S.