Repozytorium
Wyszukaj
Kolekcje
Inne
Aqua(ethylenedisulfonato)europium(II) [Eu(O3SC2H4SO3)(H2O)] - structure, spectroscopy and magnetic properties.
Autorzy
Rok wydania
2013
Czasopismo
Numer woluminu
50
Strony
283-288
DOI
10.1016/j.poly.2012.10.049
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Aqua(ethylenedisulfonato)europium(II) was obtained by electrochemical reduction. The compound is polymeric and each metal cation is surrounded by six oxygen atoms from sulfonate groups and by two water molecules. The compound shows faint emission with maximum at 414.5 nm at room temperature and bright luminescence (λmax = 408 nm) at 77 K. Magnetic susceptibility measurements show that interactions between Eu2+ cations are very weak; the shortest Eu–Eu distances are in the range 5.0–5.7 Å.
Słowa kluczowe
Divalent europium, Ethylenedisulfonate, crystal structure, spectroscopy, DFT calculations, Magnetic susceptibility
Adres publiczny
http://dx.doi.org/10.1016/j.poly.2012.10.049
Strona internetowa wydawcy
Podobne publikacje
Synthesis and structure of bis(triethanolamine)europium(II) diperchlorate.
Starynowicz Przemysław
Synthesis and crystal structure of europium(II) diacetate hemihydrate, Eu(CH3COO)2·0,5H2O.
Starynowicz Przemysław
A europium(II) complex with bis-pyridino-18-crown-6.
Christoffers J., Starynowicz Przemysław