Repozytorium

Internal dynamics of (C3N2H5)5Bi2Cl11 studied by IINS,1H NMR and QC methods.

Autorzy

K. Hołderna-Natkaniec

I. Natkaniec

Ryszard Jakubas

D. Nowak

Wojciech Medycki

Rok wydania

2008

Czasopismo

Journal of Molecular Structure

Numer woluminu

891

Strony

143-150

DOI

10.1016/j.molstruc.2008.03.025

Kolekcja

Naukowa

Język

Inny

Typ publikacji

Artykuł

Streszczenie

The low temperature inelastic incoherent neutron scattering spectra of pentakis (imidazolium) undecachlorodibismuthate (III) [(C3N2H5)5Bi2Cl11] were discussed versus different models of reference structures obtained by quantum chemical calculations in the energy transfer range up to 1200 cm−1. The second moment of 1H NMR line and spin–lattice relaxation times were employed to study the internal dynamics of imidazolium cation at the ferroelectric–paraelectric phase transition.

Słowa kluczowe

Imidazolium undecachlorodibismuthate (III), Inelastic incoherent neutron scattering, DFT calculations, Internal dynamics by 1H NMR method

Adres publiczny

https://doi.org/10.1016/j.molstruc.2008.03.025

Strona internetowa wydawcy

http://www.elsevier.com

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