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Determination of the conditional association constants from the sound velocity data in binary liquid mixtures.

Autorzy

Jacek Gliński

Rok wydania

2003

Czasopismo

Journal of Chemical Physics

Numer woluminu

118

Strony

2301-2307

DOI

10.1063/1.1534579

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Two models of calculating the association constants in mixtures of two weakly interacting liquids are proposed and analyzed: one of them assumes additivity of acoustic impedance with the molar fractions of components, and the other assumes additivity of the time of transmission of the acoustic signal with the volume fractions. The models were tested for different systems, showing that the latter yields results much more reliable and closer to expectations. The presented attempt seems to be an interesting alternative way in interpreting the experimental results of sound velocity measurements in liquid mixtures.

Adres publiczny

https://doi.org/10.1063/1.1534579

Strona internetowa wydawcy

https://www.aip.org/

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