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Synthesis and structure of the mixed ligand complex of copper(II), bis(9,10-dihydro-9-oxo-10-acridineacetato)bis(imidazole)copper(II) tetrahydrate.
Autorzy
Rok wydania
2002
Czasopismo
Numer woluminu
21
Strony
2381-2385
DOI
10.1016/S0277-5387(02)01154-3
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The new ternary compound Cu(CMA)2(Him)2·4H2O (where CMA−=9,10-dihydro-9-oxo-10-acridineacetate ion) has been synthesized and investigated by X-ray analysis, UV–Vis, EPR, IR and Raman spectroscopy. Magnetic susceptibility was measured in the range 4–300 K. The crystal structure consists of neutral monomers Cu(CMA)2(Him)2 linked by intermolecular hydrogen bonds with water molecules. The copper(II) ion is in a tetragonally elongated octahedral O2N2O′2 environment. Magnetic and spectroscopic results support the X-ray data. The synthesis, crystal structure, spectroscopic and magnetic data of a new ternary complex of Cu(II) with 9,10-dihydro-9-oxo-10-acridineacetate ion and imidazole are reported.
Słowa kluczowe
Copper(II) complexes, Imidazole, proteases, 10-dihydro-9-oxo-10-acridineacetate, Crystal structures, Spectra, Magnetic measurements
Adres publiczny
https://doi.org/10.1016/S0277-5387(02)01154-3
Strona internetowa wydawcy
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