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"Normal" and "reverse" spin crossover induced by two different structural events in iron(II) coordination polymer.
Autorzy
Rok wydania
2019
Czasopismo
Numer woluminu
55
Strony
7033-7036
DOI
10.1039/c9cc02755f
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
In [Fe(ebbtr)2(CH3CN)2](CF3SO3)2·4CH3CN spin crossover is associated with the occurrence of “normal” and “reverse” hysteresis loops separated by a region of stable HS form. This results from trans–trans → gauche–trans conformational changes of ebbtr molecules and anion reorientation, which occur in different ways during cooling and during heating.
Adres publiczny
http://dx.doi.org/10.1039/c9cc02755f
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