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Inne
A Cu/Zn heterometallic complex with solvent-binding cavity, catalytic activity for the oxidation of 1-phenylethanol and unusual magnetic properties.
Autorzy
Rok wydania
2019
Czasopismo
Numer woluminu
48
Strony
17780-17791
DOI
10.1039/c9dt03304a
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Mononuclear and polymeric complexes of zinc(II) and copper(II) have been synthesized using two isomers of the hemi-salen ligand with a different mutual orientation of donor atoms. The heterometallic Cu/Zn metallocycle features a catalytic niche filled with the molecule of water and molecules of methanol. This unusual compound exhibits both pronounced catalytic activity in the reaction of oxidation of a secondary alcohol to ketone and field induced slow magnetic relaxation, which is a very rare phenomenon among Cu(II) complexes.
Adres publiczny
http://dx.doi.org/10.1039/c9dt03304a
Strona internetowa wydawcy
Podobne publikacje
2011
Heterometallic Cu/Co and Cu/Co/Zn complexs bearing rare asymmetric tetranuclear cores: synthesis, structures, and magnetic and catalytic properties toward the peroxidative oxidation of cycloalkanes.
Nesterov Dmytro S., Kokozay Vladimir N., Jezierska Julia, Pavlyuk O. V., Boča Roman, Pombeiro Armando J. L.