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Inne
A new, highly selective, water-soluble rhodium catalyst for methyl acrylate hydroformylation.
Autorzy
Rok wydania
1995
Czasopismo
Journal of Organometallic Chemistry
Numer woluminu
505
Strony
11-16
DOI
10.1016/0022-328X(95)05595-1
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Hydroformylation of methylacrylate to α-aldehyde can be achieved in a two-phase system in the presence of two new water-soluble phosphines. High yields and selectivities of α-aldehyde (ca. 80% with a α/β ratio of 1:20) were obtained. Spectroscopic studies have been carried out and some new rhodium complexes formed in situ in catalytic systems have been identified.
Adres publiczny
https://doi.org/10.1016/0022-328X(95)05595-1
Strona internetowa wydawcy
Podobne publikacje
2018
Rhodium pyrrolylphosphine complexes as highly active and selective catalysts for propene hydroformylation: the effect of water and aldehyde on the reaction regioselectivity.
Mieczyńska Ewa, Grzybek Ryszard, Trzeciak Anna M.