Repozytorium
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Kolekcje
Inne
From discrete linear ZntBu2 molecules to 1D coordination polymers and 2D fabrics.
Autorzy
Rok wydania
2007
Czasopismo
Journal of the American Chemical Society
Numer woluminu
129
Strony
3096-3098
DOI
10.1021/ja067229k
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
We have authenticated the molecular and crystal structure of ZntBu2 and constructed the unprecedented 2D fabric structure using the tert-butylzinc molecules and 1,2-bis(4-pyridyl)ethane as building blocks. The X-ray crystal structure analysis revealed that the inorganic−organic polymeric chains were weaving to form the fabric structure by the concerted C−H···π interactions involving the pyridine rings. Subtle factors governing self-assembly processes leading to a fabric structure are discussed.
Adres publiczny
http://dx.doi.org/10.1021/ja067229k
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