Repozytorium

Self-assembly of dialkyltin(IV) moieties and a thiosemicarbone to a trinuclear macrocycle and the unprecedented formation of two pseudo-polymorphs with different cavities.

Autorzy

Dimitra Kovala-Demertzi

Joanna Wiecek

J. C. Plakatouras

Zbigniew Ciunik

Rok wydania

2008

Czasopismo

CrystEngComm

Numer woluminu

10

Strony

1291-1295

DOI

10.1039/B809216H

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

The reaction of dimethyltin(IV)oxide with pyruvic acid thiosemicarbazone (H2pt) and subsequent recrystallization from THF leads to the formation two pseudo-polymorphs based on triangular [(CH3)2Sn(pt)]3 units; one of them [(CH3)2Sn(pt)]3.3THF (1) with tubular cavities while the other [(CH3)2Sn(pt)]3.1.5THF (2) is a H-bonded 3D network with truncated tetrahedral cavities.

Adres publiczny

https://doi.org/10.1039/B809216H

Strona internetowa wydawcy

https://www.rsc.org/