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Friedel–Crafts acylation of antiaromatic norcorroles: electronic and steric modulation of the paratropic current.
Autorzy
Rok wydania
2021
Czasopismo
Numer woluminu
8
Strony
3639-3652
DOI
10.1039/d1qo00621e
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Acyl chlorides react with norcorrolatonickel(II) in dichloromethane in the presence of AlCl3 at room temperature affording two isomeric monoketone derivatives in moderate yields. For acetyl chloride, also diketones were detected and separated. Spectroscopic and electrochemical characterization studies were corroborated using DFT calculations.
Adres publiczny
http://dx.doi.org/10.1039/d1qo00621e