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Helical bis(N-confused porphyrins) with subunits fused by double orthometalation with platinum: adaptability of an apparently rigid system.
Autorzy
Rok wydania
2009
Czasopismo
Angewandte Chemie - International Edition
Numer woluminu
48
Strony
8736-8739
DOI
10.1002/anie.200904289
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The flexibility of the porphyrin rings makes racemization or chiral induction still possible with helical metalated bis(N‐confused porphyrin) systems, even though the bipyrrole fragment itself is rigid. The porphyrins are peripherally doubly orthometalated with platinum(II), and a series of its oxidative addition products were also obtained (see structures of the iodomethyl adduct: gray and brown C; blue N; orange Pt; purple I).
Słowa kluczowe
helical structures, orthometalation, Oxidative addition, platinum, porphyrinoids
Adres publiczny
https://doi.org/10.1002/anie.200904289
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