Repozytorium
Wyszukaj
Kolekcje
Inne
Structural and mechanistic studies of Pd-catalyzed C–C bond formation: the case of carbonylation and Heck reaction.
Autorzy
Rok wydania
2005
Czasopismo
Coordination Chemistry Reviews
Numer woluminu
249
Strony
2308-2322
DOI
10.1016/j.ccr.2005.02.001
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The extraordinary catalytic activity of palladium in CC bond forming processes is reviewed in respect to Heck and carbonylation reactions. Examples of catalytic systems based on palladium complexes with phosphorus ligands and phosphine-free systems and based on the Pd(0) colloid are presented. The two key steps of both reaction mechanisms: first, reduction of Pd(II) to Pd(0) complexes or Pd(0) colloids and second, oxidative addition of substrates (aryl or benzyl halides) are discussed.
Słowa kluczowe
Palladium complexes, Palladium(0) colloid, Csingle bondC coupling, Heck reaction, Carbonylation reaction
Adres publiczny
https://doi.org/10.1016/j.ccr.2005.02.001
Strona internetowa wydawcy
Podobne publikacje
Monomolecular, nanosized and heterogenized palladium catalysts for the Heck reaction.
Trzeciak Anna M., Ziółkowski Józef J.
Base-free efficient palladium catalyst of Heck reaction in molten tetrabutylammonium bromide.
Pryjomska-Ray Iweta, Trzeciak Anna M., Ziółkowski Józef J.
The Heck synthesis of β‐arylated ketones catalyzed by palladium immobilized on functional polysiloxane microspheres.
Wirwis Anna, Mizerska Urszula, Cypryk Marek, Trzeciak Anna M.