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The Missing Element in the World of Macrocycles─p-Pyriporphyrin
Autorzy
Rok wydania
2026
Czasopismo
Numer woluminu
28
Strony
6060-6065
DOI
10.1021/acs.orglett.6c01338
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The missing element of the pyriporphyrin macrocycle library was synthesized and investigated. The [3 + 1] synthesis enabled the production of 24-thia- and 24-tellura-para-pyriporphyrin. The resulting macrocycles exhibit interesting conformational dynamics, analyzed using nuclear magnetic resonance (NMR) and circular dichroism (CD) spectroscopy. Further studies revealed that they act as ligands, coordinating to metal ions, including palladium(II) and ruthenium(II). Additionally, thiophene-containing derivatives and their ruthenium complexes exhibit photoluminescence properties. The palladium complexes of both macrocycles catalyze the dealkylation of tertiary amines.
Słowa kluczowe
Aromatic compounds, Macrocycles, Molecular structure, Pyridines, Pyrroles
Adres publiczny
http://dx.doi.org/10.1021/acs.orglett.6c01338
Strona internetowa wydawcy
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