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Inne
Ferrimagnetic, bimetallic chain systems: [Cu(tren)]ReCl6 and [Cu(tren)]ReCl6·2CH3OH where tren = tris(2-aminoethyl)amine.
Autorzy
Rok wydania
2003
Czasopismo
Journal of Molecular Structure
Numer woluminu
644
Strony
97-103
DOI
10.1016/S0022-2860(02)00481-7
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Reaction of copper(II) chloride with tren [tris(2-aminoethyl)amine] and tetrabutylammonium hexachlororhenate [Bu4N]2ReCl6 produced a new kind of binuclear compounds: [Cu(tren)]ReCl6 (1) and [Cu(tren)]ReCl6·2CH3OH (2) in which [ReCl6]2− anions and [Cu(tren)]2+ cations are held united by electrostatic forces. The magnetic behaviour of 1 and 2 has been investigated over the temperature range 1.7–300 K. Compound 1 behaves as a ferrimagnetic CuIIReIV bimetallic, one-dimensional chain with intrachain antiferromagnetic coupling. Compound 2 shows weak antiferromagnetic interactions within CuII–ReIV units.
Słowa kluczowe
Bimetallic complexes, Rhenium(IV), Copper(II), Ferrimagnetic chain
Adres publiczny
https://doi.org/10.1016/S0022-2860(02)00481-7
Strona internetowa wydawcy
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