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Impact of α-hydroxymethylserine residues on binding ability of dipeptides towards CuII ions.
Autorzy
Rok wydania
1996
Czasopismo
Journal of Coordination Chemistry
Numer woluminu
40
Strony
113-120
DOI
10.1080/00958979608022850
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Potentiometric and spectroscopic studies performed on the binding ability of dipeptides containing α-hydroxymethylserine have shown that presence of the hydroxylmethyl substituent on the α-carbon changes considerably stability constants and binding modes. The indirect and direct involvement of the additional hydroxyl group is likely and this protects metal-peptide complexes against hydrolysis in very basic solutions.
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