Wydział Chemii

Nader Noshiranzadeh

Rahman Bikas

Marzieh Emami

Miłosz Siczek

Tadeusz Lis

2016

Polyhedron

111

167-172

10.1016/j.poly.2016.03.023

Naukowa

Angielski

Artykuł

A new dinuclear oxidovanadium(V) complex, [(VO)₂(μ-L-κ⁴O,N,N,O)(μ-OCH₃)₂(OMe)₂]·CH₃OH (1), is synthesized by the reaction of V₂O₅ with 1,1′-((1E,1′E)-hydrazine-1,2-diylidenebis(methanylylidene))bis(naphthalen-2-ol) (H₂L) in methanol. H₂L is synthesized by two different methods: (i) from the reaction of hydrazine hydrate with 2-hydroxy-1-naphthaldehyde and (ii) from the reaction of hydrazine hydrate with 2-naphthol in the presence of formaldehyde (Mannich condensation). The ligand and its vanadium complex are characterized by elemental analysis, spectroscopic methods (FT-IR, NMR and UV–Vis) and their structures are determined by single crystal X-ray analysis. X-ray studies show that 1 is a neutral dinuclear complex of oxidovanadium(V) in which two vanadium(V) ions are connected by two methoxido bridging groups. The Schiff base ligand is coordinated to both vanadium centers by two NO-donor sets. Complex 1 is employed as initiator for oxidative coupling of 2-naphthol to produce BINOL. The effect of temperature, reaction atmosphere and solvent in catalytic reaction is studied. According to the obtained results, a mechanism is proposed for catalytic oxidative coupling reaction in the presence of complex 1.

Dinuclear oxidovanadium(V), Schiff base ligand, Oxidative coupling, BINOL synthesis, Catalytic coupling

http://dx.doi.org/10.1016/j.poly.2016.03.023

http://www.elsevier.com