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Inne
Cryospectroscopic evidence of trimer formation between halothane and trimethylamine, stabilized by hydrogen and halogen bonds.
Autorzy
Rok wydania
2021
Czasopismo
Journal of Molecular Structure
Numer woluminu
1243
Strony
130766/1-130766/4
DOI
10.1016/j.molstruc.2021.130766
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The reversible interaction of halothane (C2HBrClF3) with negatively charged local areas of molecular targets is defined in a large extent by the proton donor ability of CH group. This interaction leads to the formation of a hydrogen bond of the CH … B type. In the presence of heavy halogen atoms in the CHClBr group, the CX … B halogen bond can act as an alternative or additional target grip option. The results obtained by the cryospectroscopy method for solutions of halothane with large excess of trimethylamine in liquefied krypton suggest the trimer formation, stabilized by hydrogen and halogen bonds between this volatile anesthetic and electron donor targets.
Słowa kluczowe
FTIR cryospectroscopy, Halothane, Trimethylamine, H – bond, Halogen bond, ab initio calculations
Adres publiczny
http://dx.doi.org/10.1016/j.molstruc.2021.130766
Strona internetowa wydawcy
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