Repozytorium
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Kolekcje
Inne
Direct synthesis of linear trinuclear M2II MnII complexes with acetate and N—N donor ligands.
Autorzy
Rok wydania
2013
Czasopismo
Journal of Molecular Structure
Numer woluminu
1038
Strony
211-215
DOI
10.1016/j.molstruc.2013.01.048
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Two novel heterometallic complexes with general formula [M2Mn(OAc)6L2], where M = Cd (1), Cu (2) and L = 2,2'-bipyridyl (bpy) for (1), 1,10-phenanthroline (phen) for (2), were obtained using "direct synthesis" approach. Trinuclear molecular structure of the complexes was determined by single crystal X-ray analysis. EPR studies of 2 indicate that the coordination environment in Cu(II) equatorial plane remains unchanged in solution as compared to the initial compound. Due to low volatility of phen the products of its decomposition probably remain on the surface of metal oxides and, therefore, in contrary to previously studied bpy-containing complexes, the compounds with phen are not suitable precursors for binary oxides preparation.
Słowa kluczowe
manganese, Direct synthesis, crystal structure, EPR study, Thermal analysis
Adres publiczny
http://dx.doi.org/10.1016/j.molstruc.2013.01.048
Strona internetowa wydawcy
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