Mapa strony Przejdź do treści

Repozytorium

Wyszukaj

Kolekcje

Inne

New silver BioMOFs driven by 1,3,5-triaza-7-phosphaadamantane-7-sulfide (PTA=S): synthesis, topological analysis and antimicrobial activity.

Autorzy

Sabina W. Jaros

Piotr Smoleński

Silva M. Fátima. C. Guedes da

Magdalena Florek

Jarosław Król

Zdzisław Staroniewicz

Armando J. L. Pombeiro

Alexander M. Kirillov

Rok wydania

2013

Czasopismo

CrystEngComm

Numer woluminu

15

Strony

8060-8064

DOI

10.1039/C3CE40913A

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Two new bioactive silver–organic frameworks [Ag(μ3-PTAS)]n(NO3)n·nH2O (1) and [Ag4(μ4-PTAS)(μ5-PTAS)(μ2-SO4)2(H2O)2]n·2nH2O (2) were easily assembled, thus opening up the application of PTAS as a versatile N,S-building block in the crystal engineering of MOFs. The obtained products reveal infinite 3D networks driven by multiply bridging PTAS spacers that adopt unprecedented N2S-coordination modes. The topological analysis of 1 discloses an uninodal 3-connected net with the srs (SrSi2) topology, whereas 2 features a pentanodal 3,4,5-connected net with a hitherto undocumented topology. Apart from representing the first MOFs derived from PTAS, the compounds 1 and 2 display notable antibacterial and antifungal activities.

Adres publiczny

http://dx.doi.org/10.1039/C3CE40913A

Strona internetowa wydawcy

https://www.rsc.org/

Podobne publikacje
2019

Light-stable polypyridine silver(i) complexes of 1,3,5-triaza-7-phosphaadamantane (PTA) and 1,3,5-triaza-7-phosphaadamantane-7-sulfide (PTA=S): significant antiproliferative activity of representative examples in aqueous media.

Jaros Sabina W., Śliwińska-Hill Urszula, Białońska Agata, Nesterov Dmytro S., Kuropka Piotr, Sokolnicki Jerzy, Bażanów Barbara, Smoleński Piotr

2014

Aliphatic dicarboxylate directed assembly of silver(I) 1,3,5-triaza-7-phosphaadamantane coordination networks : topological versatility and antimicrobial activity.

Jaros Sabina W., Guedes da Silva M. Fátima. C., Florek Magdalena, Conceição Oliveira M., Smoleński Piotr, Pombeiro Armando J. L., Kirillov Alexander M.

2013

New water-soluble polypyridine silver(I) derivatives of 1,3,5-triaza-7-phosphaadamantane (PTA) with significant antimicrobial and antiproliferative activities.

Smoleński Piotr, Jaros Sabina W., Pettinari Claudio P., Lupidi Giulio, Quassinti Luana, Bramucci Massimo, Vitali Luca A., Petrelli Dezemona, Kochel Andrzej, Kirillov Alexander M.