Wydział Chemii

Rafał Janicki

Anna Mondry

Przemysław Starynowicz

2017

Coordination Chemistry Reviews

340

98-133

10.1016/j.ccr.2016.12.001

Naukowa

Angielski

Artykuł

Rare earth carboxylates constitute an enormous group of compounds with various structures and properties. The carboxylate group may be bonded to the metal cations in several ways. The structural aspects of the coordination modes are presented and discussed from the statistical point of view and the most typical groups of carboxylate complexes are reviewed. Data concerning the thermodynamics of formation of the lanthanide, mostly Eu(III), complexes, have been aggregated and briefly analyzed. The electronic spectroscopy of lanthanide carboxylates, mostly focused on analysis of hypersensitive transitions, is discussed for simple carboxylates, acyclic aminopolycarboxylates and dipicolinates, as exemplary systems.

rare earths, Carboxylate, structure, Thermodynamic properties, Hypersensitive transitions

http://dx.doi.org/10.1016/j.ccr.2016.12.001

http://www.elsevier.com