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1,2‐Dibromoarylalkanes from Simple Arylalkanes. 2,3‐Dichloro‐5,6‐dicyano‐1,4‐benzoquinone‐Mediated One‐Pot Reaction
Autorzy
Rok wydania
2025
Czasopismo
European Journal of Organic Chemistry
Numer woluminu
28
Strony
e202500531/1-e202500531/5
DOI
10.1002/ejoc.202500531
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The presented reaction protocol for the bromination of arylalkanes gives the products of 1,2-dibromination at the alkane chain. This one-pot process is carried out under mild conditions using 2,3-dichloro-5,6-dicyano-1,4-benzoquinone , blue light (470 nm), and a manganese catalyst based on a porphyrin skeleton. In the case of an analogous reaction carried out without adding bromine, the products oxidised at the benzylic C-H position are obtained.
Słowa kluczowe
arylalkanes, bifunctionalisation, dibromination, oxidation, porphyrin catalyst
Adres publiczny
http://dx.doi.org/10.1002/ejoc.202500531
Strona internetowa wydawcy
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