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Inne
Carbonyl complexes of molybdenum and their catalytic activity.
Autorzy
Rok wydania
2012
Czasopismo
Numer woluminu
16
Strony
3-15
DOI
10.2174/138527212798993112
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
This is a review of the published papers that focus on the reactivity of carbonyl complexes of molybdenum in low oxidation states (usually zero or two) and possible applications of molybdenum complexes as precursors of catalysts in different reactions of unsaturated organic substrates such as alkenes and alkynes. The following reactions are analyzed: metathesis, metathesis polymerization, free radical reactions of alkenes, hydrogenation, hydrosilylation, hydrogermylation, hydrostannation, hydroarylation, asymmetric allylic alkylation, and epoxidation. In addition to the interesting practical aspects of these catalytic reactions, they provide additional insights into molybdenum chemistry.
Słowa kluczowe
Hydrostannation, Metathesis, asymmetric allylic alkylation, bidentate phosphine ligands, diphenylphosphinoethane (dppe), diphenylphosphinomethane (dppm), diphenylphosphinopropane (dppp), epoxidation, hydroarylation, hydrogenation, hydrogermylation, hydrosilylation, hydrostannation, hydrostannation reaction, molybdenum carbonyl complexes
Adres publiczny
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