Repozytorium

Chloramphenicol glycoside derivative: a way to overcome its antimicrobial resistance and toxicity

Autorzy

Mariusz Dziadas

Natalia Pachura

Anna Duda-Madej

Mateusz Garbicz

Tomasz Gębarowski

Alicia Domínguez-Martín

Magdalena Rowińska-Żyrek

Rok wydania

2025

Czasopismo

Carbohydrate Research

Numer woluminu

550

Strony

109387/1-109387/7

DOI

10.1016/j.carres.2025.109387

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Triggered by the urgent need to tackle the global crisis of multidrug-resistant bacterial infections, in this work, we present a way to overcome chloramphenicol resistance by introducing modifications based on the glycosylation of its hydroxyl groups. The synthesized derivatives demonstrate complete resistance to the action of recombinant chloramphenicol acetyltransferase (CAT) from Escherichia coli and efficacy against methicillin-resistant Staphylococcus aureus (MRSA), Escherichia coli ESBL, and Pseudomonas aeruginosa ATCC 27853. Glycosylation gives chloramphenicol an additional advantage - the stable glycosidic form is less toxic to human dermal fibroblasts and has significantly better water solubility than non-glycosylated chloramphenicol. Using a specific glycosidase, chloramphenicol can be almost immediately released from the stable prodrug at the site of polybacterial infections.

Adres publiczny

http://dx.doi.org/10.1016/j.carres.2025.109387

Strona internetowa wydawcy

http://www.elsevier.com