Repozytorium
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Inne
Crystal structure of CsUCl4·3H2O.
Autorzy
Rok wydania
1991
Czasopismo
Journal of the Less-Common Metals
Numer woluminu
175
Strony
347-352
DOI
10.1016/0022-5088(91)90021-U
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Dark red-brown CsUCl4 . 3H2O crystallizes in the monoclinic crystal system (a = 711.6(1) pm, b = 867.2(2) pm, c = 807.1(2) pm; β = 99.28(3)^o, space group P21m, Z = 2). Uranium has a coordination number of nine (tricapped trigonal prism) consisting of six chlorine atoms and three oxygen atoms (representing water) with mean distances of 295.7 and 255.2 pm respectively. Caesium is surrounded by eight chlorine atoms in the shape of a distorted cube which is capped by two water ligands, the mean Cs-Cl distance being 360.2 pm.
Adres publiczny
https://doi.org/10.1016/0022-5088(91)90021-U
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