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Solution studies of some new oxamides – co-ordination behaviour towards Cu(II) ions.
Autorzy
Rok wydania
2007
Czasopismo
Journal of Inorganic Biochemistry
Numer woluminu
101
Strony
1505-1516
DOI
10.1016/j.jinorgbio.2007.06.023
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The co-ordination chemistry of some new oxamides towards Cu(II) ions was studied using various techniques: potentiometry, voltammetry, spectroscopy (UV–Vis, CD and EPR) and ESI–MS spectrometry. All tested compounds chelate the copper(II) ions with formation of 1:1 and 1:2 (metal-to-ligand ratio) complexes. The Cu(II) ions are bound by 1N, 2N or 3N nitrogen donor systems. Additionally, an unusual co-ordination to amide N-atoms without additional anchoring site is suggested. The 14N hyperfine splitting observed for the system ox6–Cu(II) above pH 10 clearly indicates the involvement of at least three N donor atoms in the copper ion binding. Moreover, the surrounding by three amide-N and one carbonyl-O stabilizes the high oxidation state of copper(III), although such complexes are very unstable in solution.
Słowa kluczowe
Oxamides, Copper(II), Copper(III), Electrochemistry, Spectroscopy
Adres publiczny
https://doi.org/10.1016/j.jinorgbio.2007.06.023
Strona internetowa wydawcy
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