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A novel heterobimetallic W-Ge compound. X-ray crystal structure of [W(μ-Cl) (GeCl3)(CO)3(η4-C7H8)].
Autorzy
Rok wydania
2002
Czasopismo
Inorganic Chemistry Communications
Numer woluminu
5
Strony
682-684
DOI
10.1016/S1387-7003(02)00525-7
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The new heterobimetallic complex [W(μ-Cl)(GeCl3)(CO)3(η4-C7H8)] (1) has been prepared by photochemical reaction of W(CO)6 with bicyclo[2.2.1]hepta-2,5-diene (NBD) and GeCl4. The structure of compound 1 was established by X-ray crystallography. The IR, and spectra are also described and correlated with the crystallographically observed geometry. Compound 1 is noteworthy since it is the first alkene complex of tungsten isolated in W(CO)6 – Lewis acid photocatalytic system.
Słowa kluczowe
Tungsten, Germanium, Crystal structure, Heterobimetallic compound, Alkene complex
Adres publiczny
http://doi.org/10.1016/S1387-7003(02)00525-7
Strona internetowa wydawcy
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