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Inne
Assembling novel Cd(II) complexes with multidentate nitrogen donor ligands obtained in situ from the system: zerovalent copper, cadmium oxide, 1-hydroxymethyl-3,5-dimethylpyrazole and ammonium thiocyanate.
Autorzy
Rok wydania
2013
Czasopismo
Numer woluminu
42
Strony
5960-5963
DOI
10.1039/C3DT32987A
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A novel 3D coordination polymer [Cd2(L1)2(SCN)4(MeOH)2]n (1) and monomeric [Cd(NCS)2L2] (2) (L1 = urotropine, L2 = tris(1-(3,5-dimethylpyrazolylmethyl))amine) have been prepared in a one-pot synthesis using 1-hydroxymethyl-3,5-dimethylpyrazole as the starting ligand. The most prominent feature is the formation in situ of the organic compounds: urotropine and scorpionate-tripodal ligands.
Adres publiczny
http://dx.doi.org/10.1039/C3DT32987A