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IR band shape of vs(CH) of Pentachlorethane and Bromoform.
Autorzy
Rok wydania
1981
Czasopismo
Numer woluminu
A60
Strony
407-418
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The shape of the vs(CH) absorption band of Pentachlorethane and Bromoform was measured in several aprotic solvents and neat liquids and quantitatively analyzed. The bandshape was described in terms of profile indices, asymmetry factors, correlation functions and correlation times. A pronounced, solvent dependet asymmetry of the band was detected; not only the half-widths, but also the intensities and profiles or both sides differ markedly. A discussion of possible shaping mechanisms reveals that the bandshape is dominated by vibrational relaxation.
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