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A ferroelectric inorganic-organic hybrid based on NLO-phore stilbazolium.
Autorzy
Rok wydania
2009
Czasopismo
Journal of Materials Chemistry
Numer woluminu
19
Strony
2179-2183
DOI
10.1039/B819473D
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A ferroelectric inorganic–organic hybrid based on in situ substituted stilbazolium cation (TAMS2+ = trimethylamino-N-methyl stilbazolium) has been obtained. Single-crystal X-ray structure analysis demonstrates that the NLO-phore organic component of the complex is embedded into the inorganic polymeric [Bi2Cl8]2− framework and shows a polar arrangement with the cooperation of the nonsymmetric inorganic component. The measurement of ferroelectric and nonlinear optical properties show typical ferroelectricity and second harmonic generation (SHG) responses as well as a significant improvement of the laser damage threshold and thermal stability of relative organic material.
Adres publiczny
https://doi.org/10.1039/B819473D
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