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Kolekcje
Inne
Spectroscopic studies and crystal structure of a dimeric Zn(II) complex with diethyl (pyridin-2-ylmethyl)phosphate.
Autorzy
Rok wydania
2010
Czasopismo
Journal of Coordination Chemistry
Numer woluminu
63
Strony
3764-3771
DOI
10.1080/00958972.2010.520710
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The crystal structure of [Zn2(2-pmOpe)2Cl4] (2-pmOpe = diethyl (pyridin-2-ylmethyl)phosphate) was determined by X-ray-diffraction method. The compound was also characterized by IR, far-IR, 1H, and 31P NMR spectroscopy. In this compound, 2-pmOpe is a bidentate N,O-bridging ligand and Zn(II) are slightly distorted tetrahedral ZnNOCl2. Zn(II) ions are doubly bridged by the 2-pmOpe ligands, resulting in a dinuclear species. The structure is stabilized by intermolecular C–H ··· O and C–H ··· Cl hydrogen bonds. The spectral properties are in agreement with the structural data.
Słowa kluczowe
Zn(II), Phosphoric acid ester, N, O-donor ligand, crystal structure, Spectroscopic properties
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