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Inne
Preparation and structure of di-(μ-salicylato-0,0') - bis(1,5cyclooctadiene)-dirhodium(I).
Autorzy
Rok wydania
1994
Czasopismo
Numer woluminu
13
Strony
655-658
DOI
10.1016/S0277-5387(00)84742-7
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Di-(μ-salicylato-O,O′)-bis(1,5-cyclooctadiene)dirhodium(I) complex of the formula [Rh(HOC6H4CO2 (COD)]2 (COD = 1,5-cyclooctadiene), has been obtained in the reaction of [RhCl(COD)]2 with silver salicylate. It has a dimeric structure with two bridging carboxylate groups, two terminally bounded COD and RH ⋯ Rh distance of 3.325(3) Å. The α-hydroxyl group of the salicylate ligands forms intramolecular hydrogen bonding with the nearest oxygen of carboxylate group.
Adres publiczny
https://doi.org/10.1016/S0277-5387(00)84742-7
Strona internetowa wydawcy
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