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Inne
New iminophosphine–Ru(II) complexes and their application in hydrogenation and transfer hydrogenation.
Autorzy
Rok wydania
2014
Czasopismo
Applied Organometallic Chemistry
Numer woluminu
28
Strony
768-772
DOI
10.1002/aoc.3196
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Ruthenium complexes [RuCl2L2] were prepared by treating [RuCl2(p-cymene)]2 with structurally similar N-(2-(diphenylphosphino)benzylidene)-3-methylpyridin-2-amine, 4-(2-(diphenylphosphino)benzylideneamino)-3-methylphenol and 4-(2-(2-(diphenylphosphino)benzylideneamino)ethyl)phenol refluxed in toluene. These complexes were used as catalysts for the transfer hydrogenation of acetophenones in 2-propanol and for the direct hydrogenation of styrenes under hydrogen pressure. The results of the catalytic studies provide evidence that these complexes function as excellent catalysts for hydrogenation and transfer hydrogenation
Słowa kluczowe
iminophosphine, ruthenium complexes, hydrogenation, transfer hydrogenation
Adres publiczny
http://dx.doi.org/10.1002/aoc.3196
Strona internetowa wydawcy
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