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Inne
Critical slowing down of low-frequency dielectric relaxation in ferroelectric (C3N2H5)5Bi2Cl11.
Autorzy
Rok wydania
2005
Czasopismo
Journal of Physics-Condensed Matter
Numer woluminu
17
Strony
411-417
DOI
10.1088/0953-8984/17/41/L03
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Dielectric dispersion studies in the frequency range between 220 Hz and 1 MHz have been performed on pentakis(imidazolium) undecachlorodibismuthate(III), (C3N2H5)5Bi2Cl11, single crystals. The measurements have been made over the temperature range between 300 and 140 K. It is found that the dielectric dispersion, observed along the b-axis of the monoclinic symmetry (P 21/c), is monodispersive between 166.5 and 168 K, and polydispersive in the close vicinity of Tc = 166 K, for T<Tc + 0.2 K. The observed dielectric dispersion is analysed using a single relaxation mode of the Debye type. Over the paraelectric phase the process of the dielectric critical slowing down is observed. This is characteristic of the order–disorder ferroelectric phase transition.
Adres publiczny
https://doi.org/10.1088/0953-8984/17/41/L03
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