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Inne
H-spirophosphoranes-promising ligands in transition metal chemistry, an outlook of their coordination and catalytic properties.
Autorzy
Rok wydania
2013
Czasopismo
Coordination Chemistry Reviews
Numer woluminu
257
Strony
1039-1048
DOI
10.1016/j.ccr.2012.09.025
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The paper gives a short survey on the coordination properties of H-spirophosphoranes towards transition metals. The emphasis is on the application of H-spirophosphorane complexes in catalysis. Spirophosphoranes supported by transition metals, palladium or rhodium, have been identified as ligands in metal-catalysed enantioselective catalysis; connected to palladium centres, they exhibit catalytic properties in cross-coupling reactions. Rhenium complexes incorporating spirophosphoranes appear to act as excellent co-catalysts in oxidation reactions. It is demonstrated how fine tuning within the structure of phosphorus ligands can determine the catalytic properties of transition metal complexes.
Słowa kluczowe
H-spirophosphoranes, Phosphorus ligands, Transition metal complexes, Catalysis, Oxidation reaction, Cross-coupling
Adres publiczny
http://dx.doi.org/10.1016/j.ccr.2012.09.025
Strona internetowa wydawcy
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