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Serendipitous synthesis found in the nuances of homoleptic zinc complex formation.
Autorzy
Rok wydania
2018
Czasopismo
Numer woluminu
57
Strony
8169-8180
DOI
10.1021/acs.inorgchem.8b00550
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A series of aminophenolate and aminonaphtholate homoleptic zinc complexes were obtained using a simple and unique synthetic strategy. A rigorous analysis of the byproduct supported modifications of the main course of the bis-chelation reaction. Controlled alcoholysis was followed by alternation and controlled anaerobic hydrolysis of ethyl-zinc aminophenolate or aminonaphtholate complexes. This new and intriguing reaction yielded a new class of zinc corona complexes. All the synthesized complexes were fully characterized in the solid state and in solution using X-ray and spectroscopic methods as well as density functional theory calculations.
Adres publiczny
https://doi.org/10.1021/acs.inorgchem.8b00550
Strona internetowa wydawcy
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