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Reaction of N≡W(OtBu)3 with σ3λ5-phosphoranes. The [2 + 2] cycloaddition across the W≡N triple bond results in the first representative of an inorganic four-membered metallacycle with conjugated endo- and exocyclic double bonds.
Autorzy
Rok wydania
2012
Czasopismo
Numer woluminu
41
Strony
5132-5136
DOI
10.1039/c2dt12492k
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The reactions of N≡W(O(t)Bu)(3) with the low-coordinate phosphorus compounds (Me(3)Si)(2)NP(NSiMe(3))(2) (I) and (Me(3)Si)(2)NPS(N(t)Bu) (II) were studied. Quantum chemical calculations were used to determine why Mo- and W-containing compounds with the same composition have different molecular structures.
Adres publiczny
http://dx.doi.org/10.1039/c2dt12492k
Strona internetowa wydawcy
Podobne publikacje
2011
Reactions of (iPrO)3M≡M(OiPr)3 (M = Mo, W) with low-coordinate phosphorus compounds. Formation of the first four-membered planar metallacycles, containing an M≡M triple bond.
Kovalenko Oleksandr O., Brusylovets Oleksii A., Kinzhybalo Vasyl V., Lis Tadeusz, Brusilovets A. I.