Repozytorium

Synthesis, crystal structure and spectroscopic characterization of heterometallic Cu/Mo complexes obtained under mild conditions.

Autorzy

Halyna I. Buvailo

Valeriya G. Makhankova

Vladimir N. Kokozay

Irina V. Omelchenko

Svitlana V. Shishkina

Julia Jezierska

Rok wydania

2018

Czasopismo

Journal of Molecular Structure

Numer woluminu

1167

Strony

209-214

DOI

10.1016/j.molstruc.2018.04.094

Kolekcja

Naukowa

Język

Angielski

Typ publikacji

Artykuł

Streszczenie

Two novel heterometallic compounds, namely, {[Cu(5,5′-Me2bpy)2]2MoO4}(NO3)2·3H2O (1) and [Cu(phen)2Mo2O7(phen)]·{[Cu(phen)2]2MoO4}(NO3)2·15H2O (2), where phen = 1,10-henantroline, 5,5′-Me2bpy = 5,5′-dimethyl-2,2′-bipyridine, have been isolated under mild conditions. The influence of the copper source and organic ligands on the products composition has been investigated. Both compounds were characterized by elemental, TG/DTA and single crystal X-ray diffraction analyses, IR and EPR spectroscopies.

Słowa kluczowe

Heterometallic complexes, Molybdate, crystal structure, EPR spectroscopy

Adres publiczny

https://doi.org/10.1016/j.molstruc.2018.04.094

Strona internetowa wydawcy

http://www.elsevier.com

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