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Iron and copper complexes of tetraphenyl-m-benziporphyrin: reactivity of the internal C—H bond.
Autorzy
Rok wydania
2004
Czasopismo
Numer woluminu
43
Strony
4118-4120
DOI
10.1021/ic049821l
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Iron and copper complexes of tetraphenyl-m-benziporphyrin (TPmBPH)H have been prepared and structurally characterized. The iron system, (TPmBPH)FeIIBr, contains a high-spin Fe(II) center. In the solid state the complex forms dimeric units linked by weak CH···Br hydrogen bonds. The Cu complex contains a tetrameric copper cluster with a Cu2Cl42- unit bridging two [(TPmBPCl)CuII]+ fragments. The formation of (TPmBPCl)H represents an example of copper-catalyzed chlorination on the internal carbon atom of (TPmBPH)H.
Adres publiczny
https://doi.org/10.1021/ic049821l
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