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[Fe19] "Super-lindqvist" aggregate and large 3D interpenetrating coordination polymer from solvothermal reactions of [Fe2(OtBu)6] with ethanol.
Autorzy
Rok wydania
2015
Czasopismo
Angewandte Chemie - International Edition
Numer woluminu
54
Strony
10361-10364
DOI
10.1002/anie.201503647
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
The syntheses, crystal structures, and physical properties of [HFe19O14(OEt)30] and {Fe11(OEt)24}∞ are reported. [HFe19O14(OEt)30] has an octahedral shape. Its core with a central Fe metal ion surrounded by six μ6‐oxo ligands is arranged in the rock salt structure. {Fe11(OEt)24}∞ is a mixed‐valence coordination polymer in which FeIII metal ions form three 3D interpenetrating (10,3)‐b nets. The arrangement of the FeIII ions can also be compared to that of Si ions in α‐ThSi2. Thus, the described structures are at the interface between molecular and solid‐state chemistry.
Słowa kluczowe
Coordination polymer, Iron, Polyoxometalates, single-molecule magnets, Solvothermal synthesis
Adres publiczny
http://dx.doi.org/10.1002/anie.201503647
Strona internetowa wydawcy
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