Repozytorium
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Kolekcje
Inne
Variation of emission color of Y3Al5O12:Ce induced by thermal treatment at reducing atmosphere.
Autorzy
Rok wydania
2008
Czasopismo
Journal of Alloys and Compounds
Numer woluminu
451
Strony
582-585
DOI
10.1016/j.jallcom.2007.04.116
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Nanocrystalline powders of Y3Al5O12:Ce (YAG:Ce) were prepared using Pechini technique and precipitation with urea at 80–90 °C. It was shown that material obtained using Pechini procedure, after heating at 900–1000 °C is crystallographically pure, while that made with urea is contaminated with Y4Al2O9 and YAlO3. For all powders, heating at reducing atmosphere of nitrogen–hydrogen mixture at 1000 °C caused a red shift of the Ce3+ luminescence by about 20–25 nm. The effect was stronger for the powder prepared with urea. Also this powder was characterized by a longer decay time of the Ce3+ emission indicating the treatment at reducing atmosphere diminished nonradiative relaxation probability of the excited electrons.
Słowa kluczowe
YAG:Ce, Luminescence, Emission color, White LED
Adres publiczny
https://doi.org/10.1016/j.jallcom.2007.04.116
Strona internetowa wydawcy
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