Repozytorium
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Kolekcje
Inne
Structure and magnetic properties of a new binuclear copper(II) complex of a tripodal oxime.
Autorzy
Rok wydania
2014
Czasopismo
Journal of Molecular Structure
Numer woluminu
1059
Strony
265-270
DOI
10.1016/j.molstruc.2013.12.001
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
Perchlorate salt of a new binuclear [Cu2] cationic complex (1) with tris(1-propan-2-onyl oxime)amine acting as a ligand is introduced. In each complex cation two Cu2+ cations are linked by oxime groups from two ligands, whereas two remaining oxime groups per ligand remain non-deprotonated and participate in bifurcated O–H⋯O hydrogen bonds. Cu2+ ions are strongly antiferromagnetically coupled with singlet–triplet energy gap of about 2J = −750 cm−1, giving rise to interesting EPR properties.
Słowa kluczowe
Copper(II), Crystal structure, Magnetic properties, Antiferromagnetic coupling, EPR
Adres publiczny
http://dx.doi.org/10.1016/j.molstruc.2013.12.001
Strona internetowa wydawcy
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