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Unusual slow magnetic relaxation in a mononuclear copper(II) complex
Autorzy
Rok wydania
2022
Czasopismo
Numer woluminu
51
Strony
5612-5616
DOI
10.1039/d2dt00023g
Kolekcja
Język
Angielski
Typ publikacji
Artykuł
A hexacoordinate Cu(II) complex with the {CuO4O′N} donor set shows an intermolecular π–π stacking owing to which a 1D-chain structure is formed. The DC magnetic data at low temperature are consistent with the Curie law. The AC susceptibility shows a field supported slow magnetic relaxation that survives up to 7 K. The relaxation time at T = 2.0 K and BDC = 0.2 T is τ = 0.23 ms and it increases at BDC = 0.6 T to τ = 2.9 ms.
Adres publiczny
http://dx.doi.org/10.1039/d2dt00023g
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