Wydział Chemii

Janusz Drożdżyński

J. G. H. Preez

1994

Inorganica Chimica Acta

218

203-205

10.1016/0020-1693(94)03796-5

Naukowa

Angielski

Artykuł

The preparation and properties of a new uranium(III) iodo complex compound, UI₃(CH₃CN)₄, are reported. The compound belongs to the monoclinic system with a=9.6168, b=8.7423, c=7.1858 Å, γ=92.99° and V=603.31 ų. Magnetic susceptibility measurements were carried out by the Faraday method in the 6.5–300 K fange. In the 100–300 K region the compound exhibits Curie-Weiss paramagnetism with the paramagnetic constants μ_eff=3.44 BM, C=1.467 emu K mol⁻¹ and θ=−80 K. Solid state electronic absorption and reflectance spectra of the iodo complex have been recorded in the 4000–24 000 cm⁻¹ region and are discussed.

https://doi.org/10.1016/0020-1693(94)03796-5

http://www.elsevier.com