Wydział Chemii

Ewa Mieczyńska

Tomasz Borkowski

Marek Cypryk

P. Pospiech

Anna M. Trzeciak

2014

Applied Catalysis A-General

470

24-30

10.1016/j.apcata.2013.10.032

Naukowa

Angielski

Artykuł

Two palladium catalysts obtained in reaction of Pd(OAc)₂ with differently substituted triazolyl polysiloxanes were used in the Suzuki–Miyaura cross-coupling of aryl bromides with phenylboronic acid. Catalytic reactions, performed at 60 °C in a 2-propanol-water mixture, led to high yields of cross-coupling products when 2- and 4-bromotoluene, bromobenzene, and 2-bromoanisole were used as substrates. In recycling experiments, very good results were obtained in eight subsequent runs. High yield of 2-methylbiphenyl was also obtained with catalysts formed in situ, from Pd(OAc)₂ and polysiloxane. In these experiments, an inhibiting effect of free polymers containing butyl substituents on triazole rings was discovered. Under the same conditions, in the presence of polysiloxane functionalized with phenyl-substituted triazole, the yield of 2-methylbiphenyl remained on the level of 98–100%. The application of the TEM method to the catalysts recovered from the reaction mixture evidenced the presence of Pd(0) nanoparticles bonded to triazolyl polysiloxane. The participation of unstabilized Pd(0) forms in the reaction course was concluded from the results of the Hg(0) test.

palladium, Suzuki-Miyaura reaction, Functionalized polysiloxane, Pd(0) nanoparticles

http://dx.doi.org/10.1016/j.apcata.2013.10.032

http://www.elsevier.com